曙光煤矿1226综采工作面瓦斯抽采技术

采用综合应用理论分析、现场实测的方法,对山西汾西集团曙光煤矿1226高瓦斯综采工作面瓦斯来源进行了分析,提出并实施了分区段“风排+煤层钻孔抽放+裂隙带钻孔抽放”的联合瓦斯抽采技术。现场监测结果显示:1226综采工作面上隅角瓦斯浓度控制在0.45%~0.75%,回风流中瓦斯浓度控制在了0.44%~0.75%,瓦斯治理效果明显改善。     

Microplastics in soils: a review of possible sources,analytical methods and ecological impacts

Microplastics are emerging persistent pollutants that have been extensively detected in aqueous environments. Yet, scientists have little knowledge of microplastic pollution in soils. This study reviewed over 60 articles, with the following objectives: (i) to discuss sources and the global distribution of microplastics in soils; (ii) to evaluate current extraction techniques and analytical methods for microplastics in soils; and (iii) to comprehensively assess their adverse impacts on soils and soil organisms. Moreover, this review highlights the lack of research into microplastic contamination in soils as a significant knowledge gap. Research into the fate, sources and analytical techniques of soil microplastics and the interactions between soil organisms, soils and microplastics is essential in order to underpin management decisions aimed at safeguarding the ecological integrity of our soils. © 2020 Society of Chemical Industry     

COB LED自动在线点胶测试补粉机的研制

在COB(Chip On Board)LED光组件制造领域,点胶、测试和补粉关键工艺基本以手工或半自动为主。为了保证COB LED产品质量一致性、提高生产效率,研制了一种COB自动在线点胶测试及补粉一体机,实现点胶、测试、补粉生产工序的自动化生产。阐述了其工艺流程及设计总体方案,提出了荧光粉量修补方法,修正初次点胶量,实现动态调节,减少人工干预。经实验验证,该一体机可以提高点胶工艺的自动化程度,具有运行速度快、可靠性好、性能稳定等特点。     

综放高瓦斯矿井煤层瓦斯涌出量综合预测

为了成功预测竹林山煤矿综放高瓦斯矿井大采高工作面煤层瓦斯涌出量,以主采3号煤层为主要研究对象,针对3号煤层以往开采情况,通过布设测点测量其煤层瓦斯含量和了解相邻矿井瓦斯含量,采用分源预测法、回归法及统计法等预测方法得到了3号煤层瓦斯含量的分布规律,并绘制了3号煤层的瓦斯含量等值线图。对矿井不同生产时期的瓦斯含量进行预测,得到了生产前期、中期及后期采区的最大绝对瓦斯涌出量和最大相对瓦斯涌出量,说明了竹林山煤矿各个时期均属于高瓦斯矿井。     

Synthesis and characterization of [Zn(acetate)2(amine)x] compounds (x=1 or 2) and their use as precursors to ZnO

As an obvious candidate for a p-type dopant in ZnO, nitrogen remains elusive in this role. Nitrogen containing precursors are a potential means to incorporate nitrogen during MOCVD growth. One class of nitrogen-containing precursors are zinc acetate amines, yet, they have received little attention. The synthesis and single crystal X-ray structure of [Zn(acetate)₂(en)], and the synthesis of [Zn(acetate)₂(en)₂], [Zn(acetate)₂(benzylamine)₂], [Zn(acetate)₂(butylamine)₂], [Zn(acetate)₂(NH₃)₂], and [Zn(acetate)₂(tris)₂], where en=ethylenediamine and tris=(tris[hydroxymethyl]aminomethane) are reported. The compounds were characterized by thermogravimetric analysis and pyrolyzed in air and inert gas to yield ZnO. These compounds are useful single source precursors to ZnO bulk powders by alkali precipitation and ZnO thin films by spray pyrolysis. The amine bound to the zinc influences the ZnO crystal size and shape and acts as a nitrogen donor for preparing nitrogen-doped ZnO during alkali precipitation. Thin films of ZnO prepared by spray pyrolysis using the precursors had a (100) preferred orientation and measured n-type to intrinsic conductivity.     

The growth of oleaginous Rhodotorula glutinis in an internal-loop airlift bioreactor by using mixture substrates of rice straw hydrolysate and crude glycerol

The conversion of lignocellulosic biomass (LCB) to microbial oils is attracting a growing amount of attention. However, the growth of the oleaginous yeast Rhodotorula glutinis on LCB hydrolysate (mainly rice straw) only will lead to a low lipid mass fraction, in the range of 10–20%. This study shows that the addition of crude glycerol to the LCB hydrolysate medium can efficiently raise the lipid mass fraction to the range of 30–40%. Crude glycerol is a by-product in the biodiesel production process. The use of renewable LCB hydrolysate and crude glycerol would greatly reduce the substrate cost for microbial oil production using R. glutinis. In addition, the results of experiments show that a low-cost airlift bioreactor is a more suitable fermentation process for the growth of R. glutinis than the use of a conventional agitation tank. When using mixed carbon sources of LCB hydrolysate with 30 kg m⁻³ of reducing sugars and 30 kg m⁻³ of crude glycerol, a maximal cell mass of 21.4 kg m⁻³ and lipid mass fraction of 58.5 ± 6.2 were achieved in an internal loop airlift bioreactor, and this process may have the potential to be applied in scale-up production.     

A Method for Systematic Assessment of Intrinsically Disordered Protein Regions by NMR

Intrinsically disordered proteins (IDPs) that lack stable conformations and are highly flexible have attracted the attention of biologists. Therefore, the development of a systematic method to identify polypeptide regions that are unstructured in solution is important. We have designed an “indirect/reflected” detection system for evaluating the physicochemical properties of IDPs using nuclear magnetic resonance (NMR). This approach employs a “chimeric membrane protein”-based method using the thermostable membrane protein PH0471. This protein contains two domains, a transmembrane helical region and a C-terminal OB (oligonucleotide/oligosaccharide binding)-fold domain (named NfeDC domain), connected by a flexible linker. NMR signals of the OB-fold domain of detergent-solubilized PH0471 are observed because of the flexibility of the linker region. In this study, the linker region was substituted with target IDPs. Fifty-three candidates were selected using the prediction tool POODLE and 35 expression vectors were constructed. Subsequently, we obtained ¹⁵N-labeled chimeric PH0471 proteins with 25 IDPs as linkers. The NMR spectra allowed us to classify IDPs into three categories: flexible, moderately flexible, and inflexible. The inflexible IDPs contain membrane-associating or aggregation-prone sequences. This is the first attempt to use an indirect/reflected NMR method to evaluate IDPs and can verify the predictions derived from our computational tools.     

Characterization of a plasma polymer coating from an organophosphorus silane deposited at atmospheric pressure for fire-retardant purposes

Protective coatings from diethylphosphatoethyltriethoxysilane (DEPETS) have been deposited on different polymer substrates in a plasma discharge operated at atmospheric pressure. Plasma polymer chemistry and structure were characterized by means of Fourier transform infrared spectroscopy (FTIR), laser desorption ionization-mass spectrometry (LDI-MS), nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM). A chemical structure of the plasma polymer has been proposed based on the coating molecular characterization. Coatings were deposited on polycarbonate (PC) and polyamide 6 (PA6) substrates. The flame retardant properties of coated substrate samples were assessed using cone calorimetry and compared to those of bare substrates. A significant increase in the time to ignition (TTI), up to +143%, was recorded after coating deposition due to the formation of a high-performance barrier layer at the surface of both polymer substrates.     

基于源质的煤基中间相小球体生成与可控演化

煤全组分族分离所得的密中质组是中间相小球体生成的来源物质（即源质）。以该源质为原料，制备煤基碳质中间相。考察了炭化过程中温度、恒温时间、氮气流速、原料进样方式和添加剂等因素对中间相小球体生成过程的影响，探讨了中间相小球体演化过程的可控性。结果表明：温度、恒温时间、进样方式是影响中间相小球体生成的主要因素，能够控制生成中间相小球体粒径大小；温度升高或恒温时间延长均会加剧原料分子的热反应，促进中间相小球体的生成和融并；大面积的融并将使粒度迅速增加，部分球体解体，球体数目下降，最终形成体中间相；进样方式主要通过影响小球体演化过程中挥发性气体的逸出及原料颗粒间热传递效率影响小球体的生成和发展；氮气流速起到辅助调控作用；添加剂的加入促进了原料成核，加速了小球体的生成。     

搪瓷承压水箱在空气源热泵中实际运用研究

随着经济的快速发展，人们的生活水平得到了显著的提升，由此，人们对生活的质量就有了更高的要求，尤其是对热水的要求，更是出现了显著的提升。当前，国内的空气源热水器行业发展的十分迅速，能够充分地满足人们对热水的需求，这使得空气源热泵在人们的生活中应用的越来越广泛。在本文中，介绍了空气源热泵的工作原理以及优点，并介绍了搪瓷承压水箱在空气源热泵中的实际应用。